Средне—щелочные алкилфенолятные присадки
DOI: 10.32758/2782-3040-2023-0-1-42-45
УДК 547.562.4:547.233
Nagiyeva E.A., Kazim-zadeh A.K., Mammadova R.A., Nasirova S.I. (Institute of Chemistry of Additives A.M. Guliyev of Azerbaijan, Baku) E-mail: aki05@mail.ru, qadirov.58@ mail.ru
Keywords: alkylphenol, ammonia, monoethanolamine, benzylamine, allylamine, formaldehyde, multifunctional additives.
Abstract. The article presents the results of research on the sintesis of medium alkaline alkylphenolate additives. Additives are calcium salts of the condensation products of alkylphenols with formaldehyde and ammonia or various amines (monoethanolamine, benzylamine and allylamine) have been synthesized and studied. The physicochemical and functional properties of the synthesized products were studied by standard methods.It has been shown that all aminomethyl derivatives of alkylphenols have multifunctional properties and are superior to their analogs ИХП-101, ИХП-109 and ВНИИНП-370 in terms of their functional properties.
In addition, the additives obtained on the basis of nonylphenol in terms of anticorrosion and antioxidant properties are somewhat superior to those obtained on the basis of alkylphenol (C8–C12) due to their homogeneous composition. Thus, all synthesized compounds are multifunctional, and additives containing a secondary nitrogen atom (calcium salt of dialkyldioxybenzylamine) and a benzyl radical at the nitrogen atom (calcium salt of N-benzyldialkyldioxybenzylamine) have the highest antioxidant efficiency.